Organometallics

Reactions of neopentylindium (III) derivatives with isopropylphosphorus compounds

OT Beachley, SHL Chao, MR Churchill…

Index: Beachley Jr.; Chao, Sun-Hua L.; Churchill, Melvyn Rowen; Lake, Charles H. Organometallics, 2001 , vol. 20, # 23 p. 4896 - 4902

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Citation Number: 7

Abstract

The reaction between KIn (CH2CMe3) 3H and ClP (i-Pr) 2 in pentane at-78° C produced a mixture of [(Me3CCH2) 2InP (i-Pr) 2] 2,(Me3CCH2) 3In⊙ P (H)(i-Pr) 2,(Me3CCH2) 3In⊙ P2 (i-Pr) 4,(Me3CCH2) 3In⊙ P (CH2CMe3)(i-Pr) 2, H2, indium metal, and KCl. The formation of all products is explained by a set of experimentally verified reactions.

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