The Stobbe Condensation with Tetralone-1. A Synthesis of 3'-Keto-3, 4-dihydro-1, 2-cyclopentenonaphthalene1

WS Johnson, HCE Johnson…

Index: Johnson; Johnson; Petersen Journal of the American Chemical Society, 1945 , vol. 67, p. 1360,1364

Full Text: HTML

Citation Number: 11

Abstract

Summary Potassium t-butoxide has been found to be an excellent agent for promoting the Stobbe condensation of a ketone with diethyl succinate. Procedures are given for the introduction of a propionic acid residue at the site of the carbonyl group of an aryl ketone. The steps involve (1) a Stobbe condensation with potassium t-butoxide,(2) acid-catalyzed decarbethoxylation of the resulting half-ester and (3) reduction. An application of the ...

Related Articles:

Prevention of manganese precipitation during the continuous selective partial oxidation of methyl aromatics with molecular oxygen in supercritical water

[Fraga-Dubreuil, Joan; Garcia-Verdugo, Eduardo; Hamley, Paul A.; Perez, Eduardo; Pearson, Ian; Thomas, W. Barry; Housley, Duncan; Partenheimer, Walt; Poliakoff, Martyn Advanced Synthesis and Catalysis, 2009 , vol. 351, # 11-12 p. 1866 - 1876]

Oxidation of. beta.-diketones with (diacetoxyiodo) benzene

[Podolesov, Bojan Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2644 - 2646]

The synthesis and applications of 5-aminolevulinic acid (ALA) derivatives in photodynamic therapy and photodiagnosis

[Dabrowski, Zbigniew; Kwasny, Miroslaw; Kaminski, Jaroslaw; Beldowicz, Maria; Lewicka, Lidia; Obukowicz, Bozena; Kaliszewski, Miron; Pirozynska, Ewa Acta Poloniae Pharmaceutica - Drug Research, 2003 , vol. 60, # 3 p. 219 - 224]

Selectivity in catalytic diol electrooxidation using a polypyridine ru (iv) complex

[Navarro, Marcelo; De Giovani, Wagner F.; Romero, Jose R. Tetrahedron, 1991 , vol. 47, # 4-5 p. 851 - 857]

More Articles...