Efficient Copper (II)??Catalyzed Transamidation of Non??Activated Primary Carboxamides and Ureas with Amines

…, S Imm, S Bähn, L Neubert, H Neumann…

Index: Zhang, Min; Imm, Sebastian; Baehn, Sebastian; Neubert, Lorenz; Neumann, Helfried; Beller, Matthias Angewandte Chemie - International Edition, 2012 , vol. 51, # 16 p. 3905 - 3909

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Citation Number: 87

Abstract

Carboxamides represent an important class of compounds found in numerous bioactive products,[1] such as top-sold medicines (ie, Lipitor, Lidoderm, Vyvanse),[2] as well as in biological and synthetic polymers (ie, proteins and nylons).[3] In addition, amides serve as versatile building blocks for the preparation of pharmaceuticals, agrochemicals, polymers, etc.[4] In general, substituted amides are prepared by substitution reactions of carboxylic ...

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