Bulletin of the Chemical Society of Japan

Oxidative Anion Metatheses in Diaryliodonium Iodides and Chlorides.

P Kazmierczak, L Skulski

Index: Kazmierczak, Pawel; Skulski, Lech Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 1 p. 219 - 224

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Citation Number: 17

Abstract

Oxidative anion metatheses in the crude title iodides and chlorides produced the corresponding pure hydrogensulfates, nitrates, tetrafluoroborates, triflates, tosylates, as well as bromides and chlorides (only from the iodides) in 54—86% yields. These procedures are easier and shorter than earlier methods. By using modified oxidative metatheses in the title iodides (in the presence of HBr or HCl) it was possible either to isolate, or to detect only, ...

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