Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates and their application to kinetic resolution

M Tokunaga, H Aoyama, J Kiyosu, Y Shirogane…

Index: Tokunaga, Makoto; Aoyama, Hiroshi; Kiyosu, Junya; Shirogane, Yuki; Iwasawa, Tetsuo; Obora, Yasushi; Tsuji, Yasushi Journal of Organometallic Chemistry, 2007 , vol. 692, # 1-3 p. 472 - 480

Full Text: HTML

Citation Number: 2

Abstract

Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates such as alkenyl esters, alkenyl ethers, and azlactones (oxazol-5 (4H)-ones) are described. These reactions were applied for kinetic resolution of chiral compounds and high selectivities were achieved with vinyl ethers of 2-substituted cyclohexanols, 1, 1′-bi-2-naphthols, 1, 1′-bi-2-phenols, and 4, 4-disubstituted azlactones. Oxidative carbon–carbon bond cleavage reactions, ...

Related Articles:

N, N '-Dichlorobis (2, 4, 6-trichlorophenyl) urea (CC-2): an efficient reagent for conversion of oximes to ketones

[Gupta, Arvind K.; Acharya, Jyotiranjan; Pardasani, Deepak; Dubey, Devendra K. Journal of Chemical Research, 2007 , # 7 p. 411 - 414]

Carbonyl Reduction of Functionalized Aldehydes and Ketones by Tri-n-Butyltin Hydride and SiO2

[Figadere; Chaboche; Franck; Peyrat; Cave Journal of Organic Chemistry, 1994 , vol. 59, # 23 p. 7138 - 7141]

Neutral, non-racemising, catalytic aerobic oxidation of alcohols

[Marko, Istvan E.; Gautier, Arnaud; Mutonkole, Jean-Luc; Dumeunier, Raphael; Ates, Ali; Urch, Christopher J.; Brown, Stephen M. Journal of Organometallic Chemistry, 2001 , vol. 624, # 1-2 p. 344 - 347]

A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-Acryloylisoborneol

[Palomo, Claudio; Oiarbide, Mikel; Garcia, Jesus M.; Gonzalez, Alberto; Lecumberri, Ainara; Linden, Anthony Journal of the American Chemical Society, 2002 , vol. 124, # 35 p. 10288 - 10289]

Rh2 (II)-Catalyzed Ester Migration to Afford 3 H-Indoles from Trisubstituted Styryl Azides

[Palomo, Claudio; Oiarbide, Mikel; Garcia, Jesus M.; Banuelos, Patricia; Odriozola, Jose M.; Razkin, Jesus; Linden, Anthony Organic Letters, 2008 , vol. 10, # 13 p. 2637 - 2640]

More Articles...