The Journal of Organic Chemistry

Preparation and Thermal Rearrangement of Poly (trimethylsilyl) phenols

GD COOPER

Index: Cooper,G.D. Journal of Organic Chemistry, 1961 , vol. 26, p. 925 - 929

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Citation Number: 26

Abstract

Previous attempts to prepare phenols having more than one wtho-or para-trimethylsilyl substituent have failed because of aryl-silicon cleavage during hydr~ lysis.~ It has been found that the aryloxytrimethylsilanes can be converted to the phenols without appreciable silicon-carbon cleavage by treating them with a concentrated solution of sodium methoxide in anhydrous methanol, diluting with water, and extracting the phenol with pentane. ...