Preparation of Diethyl 2-Alkoxymethyl-, 2-Phenylselenomethyl-and 2-Phenylthiomethylmalonate

JL Delépine, P Pecquet, M Betton…

Index: Delepine, Jean-Louis; Pecquet, Pascal; Betton, Marie-Christine; Huet, Francois Synthetic Communications, 1996 , vol. 26, # 15 p. 2819 - 2829

Full Text: HTML

Citation Number: 7

Abstract

Preparation of dialkyl 2-alkoxymethylmalonates is usually performed by ... In our hands, attempts to prepare compound la by reaction between ... Therefore we carefully examined results according to the experimental conditions. ... Me0 CO2Et EtO2C CO,Et CO2Et 3 4 ... Aco2Et "inverse Et02CCHNaC02Et + ROCH2C1 - 5 conditions" RO CO2Et ... We fustly found that addition of chloromethyl methyl ether to the sodium derivative ... 5 ("direct conditions") in refluxing THF, only led to a ...

Related Articles:

Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions: Direct synthesis of methylene-bridged bis-1, 3-dicarbonyl …

[Dai, Xiao-Jun; Xu, Xiao-Liang; Cheng, Dong-Ping; Li, Xiao-Nian Chinese Chemical Letters, 2014 , vol. 25, # 4 p. 545 - 548]

Dibromomethane as one-carbon source in organic synthesis: microwave-accelerated α-methylenation of ketones with dibromomethane and diethylamine

[Hon, Yung-Son; Hsu, Tzyy-Rong; Chen, Chun-Yan; Lin, Yi-Hui; Chang, Fong-Jong; Hsieh, Cheng-Han; Szu, Ping-Hui Tetrahedron, 2003 , vol. 59, # 9 p. 1509 - 1520]

Gold/copper-catalyzed activation of the aci-form of nitromethane in the synthesis of methylene-bridged bis-1, 3-dicarbonyl compounds

[Balamurugan, Rengarajan; Manojveer, Seetharaman Chemical Communications, 2011 , vol. 47, # 39 p. 11143 - 11145]

More Articles...