α-Naphthyltriphenylphosphonium Peroxodisulfate: A Selective and Regenerable Reagent for Oxidation of Organic Compounds

…, M Tajbakhsh, F Ramzanian-Lehmali

Index: Lakouraj, Moslem Mansour; Tajbakhsh, Mahmood; Ramzanian-Lehmali, Farhad Phosphorus, Sulfur and Silicon and the Related Elements, 2008 , vol. 183, # 6 p. 1388 - 1395

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Abstract

Alcohols, hydroquinones, tetrahydropyranyl ethers, trimethylsilyl ethers, oximes, semicarbazones, and phenylhydrazones were efficiently converted to the corresponding carbonyl compounds using α-naphthyltriphenylphosphonium peroxodisulfate (NTPPPODS) in acetonitrile at reflux conditions. This reagent could be regenerated and reused, which represents significant advantages over the known reagents.

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