Stereoselective synthesis and stereochemical determination of 2, 5??dialkylpyrrolidines and 2, 6??dialkylpiperidines

D Bacos, JP Celerier, E Marx, S Rosset…

Index: Bacos, D.; Celerier, J. P.; Marx, E.; Rosset, S.; Lhommet, G. Journal of Heterocyclic Chemistry, 1990 , vol. 27, # 5 p. 1387 - 1392

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Citation Number: 27

Abstract

Abstract ω-Alkyllactams 3 can be transformed into ω-alkyl cyclic β-enaminoesters 7 which are good precursors of insects venom alkaloids. A stereoselective synthesis of dialkylpyrrolidines and Solenopsine A is described followed by an easy stereochemical determination by 13 C nmr.

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