Palladium-catalyzed intramolecular coupling between aryl iodides and allyl moieties via thermal and microwave-assisted conditions

M Lautens, E Tayama, C Herse

Index: Lautens, Mark; Tayama, Eiji; Herse, Christelle Journal of the American Chemical Society, 2005 , vol. 127, # 1 p. 72 - 73

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Citation Number: 66

Abstract

Palladium-catalyzed intramolecular cross-coupling reactions between aryl iodides and allyl moieties were successfully demonstrated in the presence of palladium catalyst, tri-o- tolylphosphine, a tertiary amine, and water. Several kinds of trans-2, 4-disubstituted 1, 2, 3, 4- tetrahydroquinolines were synthesized in 73-88% yields with excellent diastereoselectivities. This method was further applied to a large variety of substrates to ...

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