Highly efficient carbopalladation across vinylsilane: Dual role of the 2-pyme2si group as a directing group and as a phase tag

…, K Mitsudo, T Kamei, T Koike, T Nokami…

Index: Itami; Mitsudo; Kamei; Koike; Nokami; Yoshida Journal of the American Chemical Society, 2000 , vol. 122, # 48 p. 12013 - 12014

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Citation Number: 97

Abstract

Carbopalladation, the insertion of unsaturated molecules into carbon-palladium bonds, is a critically important step in many palladium-catalyzed carbon-carbon bond-forming processes1 such as the Mizoroki-Heck reaction, 2 cyclic cascade reaction, 1d cyclooligomerization, and polymerization. We have recently been engaged in the development of removable directing groups, 3 which control the metal-mediated and- ...

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