α-Alkoxytin compounds in organic synthesis: an efficient synthesis of α-ethoxyalkenyl-and α-ethoxyalkynyl-tin compounds

A Duchêne, JP Quintard

Index: Duchene, Alain; Quintard, Jean-Paul Journal of the Chemical Society, Chemical Communications, 1987 , # 1 p. 29 - 30

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Abstract

Alkenyl-and alkynyl-aluminium reagents react with diethoxymethyltributyltin to afford the corresponding α-ethoxyalkenyl-and α-ethoxyalkynyl-tin compounds in high yields; the but-3- ynyltin derivatives has been modified to give new bis (tributyltin) precursors useful for selective organic synthesis.