Complexation Equilibria Involving Salts in Non??Aqueous Solvents: Ion Pairing and Activity Considerations

…, JW Jones, LN Zakharov, AL Rheingold…

Index: Gibson, Harry W.; Jones, Jason W.; Zakharov, Lev N.; Rheingold, Arnold L.; Slebodnick, Carla Chemistry - A European Journal, 2011 , vol. 17, # 11 p. 3192 - 3206

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Citation Number: 49

Abstract

Abstract Complexation of anions, cations and even ion pairs is now an active area of investigation in supramolecular chemistry; unfortunately it is an area fraught with complications when these processes are examined in low polarity organic media. Using a pseudorotaxane complex as an example, apparent K a2 values (=[complex]/{[salt] o−[complex]}{[host] o−[complex]}) for pseudorotaxane formation from dibenzylammonium ...