Hydrodefluorination of N-Acetylheptafluoro-2-naphthylaminebyzinc in Aqueous Ammonia: Synthetic Outcomes and Mechanistic Considerations

…, LN Shchegoleva, NV Vasil'eva, IY Bagryanskaya…

Index: Reshetov, Alexey V.; Selivanova, Galina A.; Politanskaya, Larisa V.; Beregovaya, Irina V.; Shchegoleva, Lyudmila N.; Vasil'eva, Nadezhda V.; Bagryanskaya, Irina Yu.; Shteingarts, Vitalij D. Arkivoc, 2011 , vol. 2011, # 8 p. 242 - 262

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Citation Number: 3

Abstract

Abstract Reduction of the N-acetyl derivatives of heptafluoro-2-naphthylamine and its less fluorinated analogues by zinc in aqueous NH3 has been investigated as a possible general and concise route to partially fluorinated N-(2-naphthyl) acetamides and, accordingly, 2- naphthylamines inaccessible by other ways.