Trisubstituted (stannylmethyl) lithium as a methylene double anion equivalent. Reaction with esters

…, T Igarashi, M Minomura, E Murayama

Index: Sato, Tadashi; Matsuoka, Hiroharu; Igarashi, Tsutomu; Minomura, Masafumi; Murayama, Eigoro Journal of Organic Chemistry, 1988 , vol. 53, # 6 p. 1207 - 1212

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Citation Number: 29

Abstract

1208 J. Org. Chem., Vol. 53, No. 6, 1988 of d orbitals, impart anionic character to the neighboring carbon due to the positive nature of the metals, and produce stable compounds having the metal-lithium bond, in which the group IV atoms behave as nucleophiles. However, there are still many reactions in which a large difference is observed between these two metal compounds. Citing a few examples, the stannyllithium is much more ...