Journal of Fluorine Chemistry

Reactions of HMPA with hexafluorobenzene, pentafluorochlorobenzene and pentafluorophenol

CP Zhang, QY Chen, JC Xiao

Index: Zhang, Cheng-Pan; Chen, Qing-Yun; Xiao, Ji-Chang Journal of Fluorine Chemistry, 2008 , vol. 129, # 5 p. 424 - 428

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Abstract

Hexamethylphophoramide (HMPA) reacted with hexafluorobenzene and its derivatives with good conversion to give dimethylaminated products and phosphorofluoridates, even in unfavorable reaction stoichiometries. An aromatic nucleophilic mechanism might be involved.

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