Catalytic C-phenylation of methyl acrylate with tetraphenylantimony (v) halides and carboxylates

AV Gushchin, EV Grunova, DV Moiseev…

Index: Gushchin; Grunova; Moiseev; Morozov; Shavyrin; Dodonov Russian Chemical Bulletin, 2003 , vol. 52, # 6 p. 1376 - 1379

Full Text: HTML

Citation Number: 9

Abstract

Abstract Catalytic C-phenylation of methyl acrylate to methyl cinnamate with the Ph 4 SbX complexes (X= F, Cl, Br, OH, OAc, O 2 CEt) in the presence of the palladium compounds PdCl 2, Pd (OAc) 2, Pd 2 (dba) 3, Pd (Ph 3 P) 2 Cl 2, and Pd (dppf) Cl 2 (dba is dibenzylideneacetone and dppf is bis (diphenylphosphinoferrocene)) was studied in organic solvents (MeCN, THF, DMF, MeOH, and AcOH). The highest yield of methyl cinnamate (73 ...

Related Articles:

Ceric (IV) ammonium nitrate mediated transesterification and esterification

[Stefane, Bogdan; Kocevar, Marijan; Polanc, Slovenko Synthetic Communications, 2002 , vol. 32, # 11 p. 1703 - 1707]

Contribution of cinnamic acid analogues in rosmarinic acid to inhibition of snake venom induced hemorrhage

[Aung, Hnin Thanda; Furukawa, Tadashi; Nikai, Toshiaki; Niwa, Masatake; Takaya, Yoshiaki Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 7 p. 2392 - 2396]

The One??Pot Wittig Reaction: A Facile Synthesis of α, β??Unsaturated Esters and Nitriles by Using Nanocrystalline Magnesium Oxide

[Choudary, Boyapati M.; Mahendar, Koosam; Kantam, M. Lakshmi; Ranganath, Kalluri V. S.; Athar, Taimur Advanced Synthesis and Catalysis, 2006 , vol. 348, # 14 p. 1977 - 1985]

Polymer (fiber)-supported palladium catalyst containing imidazolinyl rings and its application to the Heck reaction

[Lin, Kunhua; Song, Maoping; Cai, Dongmei; Hao, Xinqi; Wu, Yangjie Tetrahedron Letters, 2003 , vol. 44, # 20 p. 3955 - 3957]

Accelerated Heck reaction using ortho??palladated complex in a nonaqueous ionic liquid with controlled microwave heating

[Hajipour, Abdol R.; Rafiee, Fatemeh Applied Organometallic Chemistry, 2011 , vol. 25, # 7 p. 542 - 551]

More Articles...