ESR Studies of Nitrogen-centered Free Radicals, N-Aryl-N-phenylthioaminyls

Y Miura, M Kinoshita

Index: Miura,Y.; Kinoshita,M. Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 1142 - 1146

Full Text: HTML

Citation Number: 46

Abstract

A variety of substituted N-phenyl-N-phenylthioaminyls (2), Ar–\ dotN–S–Ar′, were generated by the photolysis of benzenesulfenanilides (1) in benzene in the presence of di-t- butyl peroxide or by the oxidation of 1 in benzene with lead dioxide. The ESR spectra of the radicals were completely analyzed by labeling some radicals with deuterium and with the aid of a computer simulation technique. The unpaired electron is distributed mainly on the ...