Selective oxidations by sulfur trioxide
V Mark, L Zengierski, VA Pattison…
Index: Mark,V. et al. Journal of the American Chemical Society, 1971 , vol. 93, # 14 p. 3538 - 3540
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Citation Number: 2
Abstract
Similarly, 2, 3, 4, 5, 6-pentabromotoluene yielded quantitatively pentabromobenzaldehyde, mp 281-283'. Both aldehydes were completely free of the corresponding acids, probably as a result of steric crowding in E, which prevents the removal of the third hydrogen from the benzylic carbon. The aldehyde-forming reaction seems to be characteristic of polyhalotoluenes and meta-substituted benzenes (m-xylene and mesitylene), since ...
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