The Reactions of Certain Gamma Ketonic Acids. III. Ketonic Beta Lactones

EP Kohler, WD Peterson, CL Bickel

Index: Kohler, Peterson, Bickel Journal of the American Chemical Society, 1934 , vol. 56, p. 2000,2005

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Citation Number: 3

Abstract

Summary In the reaction of propylene with sulfuric acid, no primary ester is formed. Peroxides do not cause the formation of primary normal amyl hydrogen sulfate from pentene- 1. The addition of sulfuric acid, using 85-90% acid to propylene and pentene-1, differs from the addition of hydrogen bromide in forming no primary derivatives. The addition of sulfuric acid to pentene-2 gives sulfuric esters of both pentanol-2 and pentanol-3.