Reaction of ketenes with N, N??Disubstituted 2??Aminomethylenecyclo??alkanones VI. Synthesis of N, N??Disubstituted 4??Amino??3, 4??dihydro??3, 3??dithioethyl??5, 6?? …

A Bargagna, P Schenone…

Index: Bargagna,A. et al. Journal of Heterocyclic Chemistry, 1977 , vol. 14, p. 249 - 251

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Abstract

Abstract The reaction of dithioethylketene, a new dithioalkylketene prepared in situ from dithio-ethylacetyl chloride and triethylamine, with N, N-disubstituted 2- aminomethylenecycloalkanones gave the 1, 4-cycloadducts, namely N, N-disubstituted 4- amino-3, 4-dihydro-3, 3-dithioethyl-5, 6-polymethylene-α-pyrones.

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