Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids: I. Reactivity of a …

…, AE Shumeiko, ML Kostrikin, TM Prokop'eva…

Index: Kapitanov; Belousova; Shumeiko; Kostrikin; Prokop'Eva; Popov Russian Journal of Organic Chemistry, 2013 , vol. 49, # 9 p. 1291 - 1299 Zh. Org. Khim., 2013 , vol. 49, # 9 p. 1308 - 1316,9

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Citation Number: 6

Abstract

Abstract A new functionalized gemini surfactant, 3, 3′-[2-(hydroxyimino) propane-1, 3-diyl] bis (1-dodecyl-1 H-imidazol-3-ium) dichloride, and its non-micelle-forming methyl analog, were synthesized. Nucleophilicity of the oximate group in these compounds in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids follows Brønsted relations for monomeric functionalized surfactants and non-micelle-forming ...