… of Methyl threo-2-Acetoxy-3-chloro-3-(4-methoxyphenyl) propanoate and Methyl cis-2, 3-Epoxy-3-(4-methoxyphenyl) propanoate With 3, 5-Dimethoxyphenol: …

RFC Brown, WR Jackson, TD McCarthy…

Index: Brown, Roger. F. C.; Jackson, W. Roy; McCarthy, Tom D.; Fallon, Gary D. Australian Journal of Chemistry, 1992 , vol. 45, # 11 p. 1833 - 1843

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Citation Number: 5

Abstract

Abstract Attempted syntheses of flavan-3-ols by reaction of either methyl threo-2-acetoxy-3- chloro-3-(4-methoxypheny1) propanoate (3) or methyl cis-2, 3-epoxy-3-(4-methoxypheny1) propanoate (14) with 3, 5-dimethoxyphenol failed to give the required aryl ethers. Products usually were derived from C-alkylation of the electron-rich phenol although reaction of the chloro acetate (3) with the phenoxide ion gave the furanone (5). The single-crystal X-ray ...

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