Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate
Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate structure
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Common Name | Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate | ||
|---|---|---|---|---|
| CAS Number | 42245-42-1 | Molecular Weight | 208.211 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 297.7±40.0 °C at 760 mmHg | |
| Molecular Formula | C11H12O4 | Melting Point | 69-71ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 129.2±27.4 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.2±0.1 g/cm3 |
|---|---|
| Boiling Point | 297.7±40.0 °C at 760 mmHg |
| Melting Point | 69-71ºC(lit.) |
| Molecular Formula | C11H12O4 |
| Molecular Weight | 208.211 |
| Flash Point | 129.2±27.4 °C |
| Exact Mass | 208.073563 |
| PSA | 48.06000 |
| LogP | 1.27 |
| Vapour Pressure | 0.0±0.6 mmHg at 25°C |
| Index of Refraction | 1.534 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi |
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
|
~%
Methyl 3-(4-met... CAS#:42245-42-1 |
| Literature: Svoboda, Jiri; Kocfeldova, Zuzana; Palecek, Jaroslav Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 822 - 832 |
|
~17%
Methyl 3-(4-met... CAS#:42245-42-1 |
| Literature: Hashiyama, Tomiki; Inoue, Hirozumi; Konda, Mikihiko; Takeda, Mikio Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 8 p. 1725 - 1732 |
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~%
Methyl 3-(4-met... CAS#:42245-42-1 |
| Literature: Brown, Roger. F. C.; Jackson, W. Roy; McCarthy, Tom D.; Fallon, Gary D. Australian Journal of Chemistry, 1992 , vol. 45, # 11 p. 1833 - 1843 |
|
~%
Methyl 3-(4-met... CAS#:42245-42-1 |
| Literature: Svoboda, Jiri; Kocfeldova, Zuzana; Palecek, Jaroslav Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 822 - 832 |
CAS#:5703-26-4
CAS#:105560-93-8
CAS#:106003-21-8|
Optimization of Serratia marcescens lipase production for enantioselective hydrolysis of 3-phenylglycidic acid ester.
J. Ind. Microbiol. Biotechnol. 31(11) , 525-30, (2004) Lipase production and cell growth of Serratia marcescens ECU1010 were optimized in shake flasks, with lipase production being enhanced 9.5-fold (4,780 U/l) compared with the initial activity (500 U/l)... |
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A practical procedure for the large-scale preparation of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate, a key intermediate for diltiazem.
J. Org. Chem. 67(13) , 4599-601, (2002) A practical synthesis of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate (-)-2, a key intermediate for diltiazem (1), was developed. Treatment of methyl (E)-4-methoxycinnamate 3 with chiral dioxirane, gen... |
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Highly enantioselective mukaiyama aldol reaction of alpha,alpha-dichloro ketene silyl acetal: an efficient synthesis of a key intermediate for diltiazem.
J. Org. Chem. 68(3) , 974-9, (2003) An efficient synthesis of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate (-)-2, a key intermediate for diltiazem (1), has been developed on the basis of the highly enantioselective Mukaiyama aldol reacti... |
| Methyl 3-(4-methoxyphenyl)-2-oxiranecarboxylate |
| MFCD00012316 |
| Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate |
| Methyl 3-(p-methoxyphenyl)-2,3-epoxypropionate |
| 4'-methoxy-5,6-benzoflavanone |
| EINECS 255-735-1 |
| 2-Oxiranecarboxylic acid, 3-(4-methoxyphenyl)-, methyl ester |