Synthesis and reactions of N-sulfonylamines

GM Atkins Jr, EM Burgess

Index: Atkins,G.M.; Burgess,E.M. Journal of the American Chemical Society, 1972 , vol. 94, # 17 p. 6135 - 6141

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Citation Number: 72

Abstract

Abstract: N-Sulfonylamines, a new heterocumulene system, have been synthesized by the action of triethylamine on sulfamoyl chlorides. N-Sulfonylethyhmine and N- sulfonylbenzamide have been prepared in solution and intercepted with amines to give sulfamides or with nucleophilic olefins to give 1, Zthiazetidine 1, l-dioxides when the reactions were carried out under conditions which did not favor ring opening. In several ...