The Journal of Organic Chemistry

Reactions of Perfluoroalkyl Nitriles. VI. Perfluoroacyl Imidates as Intermediates1

HC Brown, CR Wetzel

Index: Brown,H.C.; Wetzel,C.R. Journal of Organic Chemistry, 1965 , vol. 30, p. 3729 - 3733

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Citation Number: 25

Abstract

IV v VI placement of the imino group would not be expected, since, in order to break the strong double bond between the nitrogen atom and the electropositive carbon, the presence of a strong acid with the ability to protonate the nitrogen atom would be necessary. We have shown that most perfluoroacyl imidate acid salts are unstable.