Bis (methylelement) dithiooxamid-derivate von Al, Ga, In, Si, Ge und Sn; planare metallabicyclen und verdrillte strukturen

T Halder, W Schwarz, J Weidlein, P Fischer

Index: Halder, T.; Schwarz, W.; Weidlein, J.; Fischer, P. Journal of Organometallic Chemistry, 1983 , vol. 246, # 1 p. 29 - 48

Full Text: HTML

Citation Number: 1

Abstract

When trimethyl derivatives of aluminium, gallium and indium are reacted with dithiooxamides, , in a molar ratio, 2 moles of methane are set free, and monomeric bis(dimethylmetal)/dithiooxamides are formed. By 1 H NMR, IR and Raman spectroscopy, two structural isomers have been established for these metalla complexes, both with a planar molecular backbone of two fused five-membered rings, but different coordination of the two metal ...