Chemical and structural characterization of W (CO) 5OPPh2NPPh3. A novel tungsten carbonyl complex containing a phosphine oxide ligand derived from the bis ( …

DJ Darensbourg, M Pala, D Simmons…

Index: Darensbourg, Donald J.; Pala, Magdalena; Simmons, Debra; Rheingold, Arnold L. Inorganic Chemistry, 1986 , vol. 25, p. 3537 - 3541

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Abstract

(3) Bryndza, HE Organometallics 1985, 4, 1686.(4) Reese, WM; Atwood, JD Organometallics 1985, 4, 402.(5) Newman, LJ; Bergman, RG J. Am. Chem. SOC. 1985, 107, 5314. neous- catalyzed reactions. An illustrative and pertinent example to our research efforts is the methanol carbonylation to methyl formate process employing group 6 or 8 metal carbonyl catalyst~.'~,'~ Nevertheless, there are few reports of isolated and well-characterized ...

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