Synthesis of fluoro-substituted acrylic monomers bearing a functionalized lateral chain: Part 1. Preparation of sulfur-containing monomers

B Pees, A Cahuzac, M Sindt, B Ameduri…

Index: Pees; Cahuzac; Sindt; Ameduri; Paul; Boutevin; Mieloszynski Journal of Fluorine Chemistry, 2001 , vol. 108, # 2 p. 133 - 142

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Citation Number: 10

Abstract

The synthesis of sulfur-containing fluoroacrylic monomers CmF2m+ 1 (CH2) 2S (CH2) nOC (O) CH CH2 (where m= 6, 8 and n= 2–4, 11) is presented from a two-step procedure. The first deals with the radical addition of fluorinated mercaptans CmF2m+ 1 (CH2) 2SH onto ω- unsaturated alcohols leading to new ω-perfluorinated alcohols containing various polymethylene spacers CmF2m+ 1 (CH2) 2S (CH2) nOH according to the nature of the ...