Vinylborane formation in rhodium-catalyzed hydroboration of vinylarenes. Mechanism versus borane structure and relationship to silation

JM Brown, GC Lloyd-Jones

Index: Journal of the American Chemical Society, , vol. 116, # 3 p. 866 - 878

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Citation Number: 99

Abstract

... 1992, 114, 8863-9. 0 1994 American Chemical Society ... SOC., Vol. ... tentative suggestion to explain part of the pathway would be that oxidation produces a phosphine-poor complex which encourages the formation of vinylborane in a similar manner to the chemistry described for ...

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