The Journal of Organic Chemistry

Synthesis of pyrrolidines and pyrrolidinones by the rhodium complex catalyzed cyclization of unsaturated amines

JQ Zhou, H Alper

Index: Zhou, Jian-Qiang; Alper, Howard Journal of Organic Chemistry, 1992 , vol. 57, # 12 p. 3328 - 3331

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Citation Number: 40

Abstract

1 elective, and regiospecific in some instances, with steric effects playing a role in this reaction. For example, branched-chain aldehydes were obtained as the predominant or only producb when monosubstituted styrenes were used as reactants, while terminal aldehydes were favored when bulky alkyl substituents were attached to the double bond (eg, 3, 3- dimethyl-l-hexene) or when the olefin was a 1, l-disubstituted one.'One can also realize ...

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