Tetrahedron letters

Palladium-catalyzed reactions of acylzirconocene chloride with organic halides

Y Hanzawa, N Tabuchi, T Taguchi

Index: Hanzawa, Yuji; Tabuchi, Nobuhito; Taguchi, Takeo Tetrahedron Letters, 1998 , vol. 39, # 34 p. 6249 - 6252

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Citation Number: 54

Abstract

Palladium-catalyzed reactions of nonanoylzirconocene chloride 1 with aryl halide, acid halides, and allylic halides gave the acylated compounds through a nucleophilic attack of an “unmasked” acyl anion in fair to excellent yields. In an analogous way, allylic acetate gave an acyl substituted product through the reaction of 1.

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