Chemistry Letters

Unprecedented gamma-selective michael addition of tin (II) dienolates to acyclic. ALPHA.,. BETA.-unsaturated ketones.

RW Stevens, T Mukaiyama

Index: Stevens, Rodney W.; Mukaiyama, Teruaki Chemistry Letters, 1985 , p. 851 - 854

Full Text: HTML

Citation Number: 5

Abstract

Tin (II) dienolates were found to react exclusively at the gamma carbon with acyclic α, β- unsaturated ketones in the Michael sense. Either acyclic 1, 7-diketones or 2-cyclohexenol derivatives could be obtained in moderate to excellent yields by appropriate choice of ...