Collection of Czechoslovak Chemical Communications

Synthesis of eight stereoisomeric 5-(adenin-9-yl)-2, 3, 4-trihydroxypentanoic acids

A Holý

Index: Holy, Antonin Collection of Czechoslovak Chemical Communications, 1982 , vol. 47, # 11 p. 2969 - 2988

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Citation Number: 15

Abstract

Abstract Condensation of 5-Op-toluenesulfonyl-2, 3-O-isopropylidene-D-ribonolactone (XIIIb) with sodium salt of adenine afforded compound XIV which on alkaline, followed by acid, hydrolysis gave the (2R, 3R, 4R)-isomer V. The (2S, 3S, 4S)-isomer VIII was prepared analogously from the L-ribonolactone derivative XVb via the adenine derivative XVI. Compound XVIIc was transformed by reaction with adenine into 6-(adenin-9-yl)-6-deoxy- ...

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