Synthesis and characterization of perfluorohexylated poly (3, 4-ethylenedioxythiophene)

L Zuo, FL Qing, WD Meng, X Huang, S Zhang…

Index: Zuo, Liangbin; Qing, Feng-Ling; Meng, Wei-Dong; Huang, Xiaoyu; Zhang, Sen; Wu, Qiang Journal of Fluorine Chemistry, 2004 , vol. 125, # 10 p. 1441 - 1446

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Citation Number: 6

Abstract

The perfluorohexylated 3, 4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3, 4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC.

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