Journal of Organometallic Chemistry

The palladium-catalysed arylation of activated alkenes with aroyl chlorides

HU Blaser, A Spencer

Index: Blaser, Hans-Ulrich; Spencer, Alwyn Journal of Organometallic Chemistry, 1982 , vol. 233, # 2 p. 267 - 274

Full Text: HTML

Citation Number: 131

Abstract

Abstract Aroyl chlorides react with activated alkenes in presence of a tertiary amine and a catalytic amount of palladium acetate to give arylated alkenes, specifically cinnamic acid derivatives and stilbenes. The reaction involves a highly efficient decarbonylation of the aroyl chloride. High yields can be obtained at low catalyst concentration by choice of an appropriate base. The reaction is not particularly sensitive to substituents in the aroyl ...

Related Articles:

An efficient catalytic method for the Beckmann rearrangement of ketoximes to amides and aldoximes to nitriles mediated by propylphosphonic anhydride (T3P®)

[Augustine, John Kallikat; Kumar, Rajesha; Bombrun, Agnes; Mandal, Ashis Baran Tetrahedron Letters, 2011 , vol. 52, # 10 p. 1074 - 1077]

Palladium and copper complexes with oxygen–nitrogen mixed donors as efficient catalysts for the Heck reaction

[Bagherzadeh, Mojtaba; Amini, Mojtaba; Ellern, Arkady; Keith Woo Inorganica Chimica Acta, 2012 , vol. 383, p. 46 - 51]

The Aminocyclodextrin/Pd (OAc) 2 Complex as an Efficient Catalyst for the Mizoroki–Heck Cross??Coupling Reaction

[Kanagaraj, Kuppusamy; Pitchumani, Kasi Chemistry - A European Journal, 2013 , vol. 19, # 43 p. 14425 - 14431]

A novel oxidative transformation of alcohols to nitriles: an efficient utility of azides as a nitrogen source

[Rokade, Balaji V.; Malekar, Sanjeev K.; Prabhu, Kandikere Ramaiah Chemical Communications, 2012 , vol. 48, # 44 p. 5506 - 5508]

Practical one-pot conversion of aryl bromides and β-bromostyrenes into aromatic nitriles and cinnamonitriles

[Ishii, Genki; Harigae, Ryo; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2013 , vol. 69, # 5 p. 1462 - 1469]

More Articles...