Transition metal complex-catalyzed carbonylation of organic halides in N, N, N', N'-tetraalkylurea solution in the absence of added base

…, H Maekawa, S Takahashi, T Fuchikami

Index: Urata, Hisao; Maekawa, Hisayuki; Takahashi, Shigeharu; Fuchikami, Takamasa Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4320 - 4322

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Citation Number: 31

Abstract

How to replace the halogen atom of an akyl halide with another functional group by means of a transition metal catalyzed reaction remaine an unsolved problem.'Usually, the desired transformation doea not proceed because alkyl halides (eg R1CH2CH&; X= halogen atom) oxidatively add to low-valent transition metal complexes (Met) only slowly, and furthermore, 6-elimination reaction of metal halohydride (H-Met-X) from the oxidative adducts, Q- ...

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