Journal of organometallic chemistry

Palladium-catalyzed allylic alkylation of carbonucleophiles witl allylic borates or allylic alcohols and boron oxide under neutral conditions

X Lu, X Jiang, X Tao

Index: Lu, Xiyan; Jiang, Xiaohui; Tao, Xiaochun Journal of Organometallic Chemistry, 1988 , vol. 344, p. 109 - 118

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Abstract

Abstract Under neutral conditions, Pd (PPh 3) 4 catalyzes the allylic alkylation of carbonucleophiles with allylic borates in high yields. Moreover, allylic borates are formed in situ from allylic alcohols with boron oxide, and the Pd-cata; yzed allylic alkylation was achieved simply by the reaction of allylic alcohols with a nucleophile in the presence of boron oxide by one-pot procedure. The mechanisms of these reactions are discussed.

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