The Journal of organic chemistry

Palladium-catalyzed reactions of arylindium reagents prepared directly from aryl iodides and indium metal

V Papoian, T Minehan

Index: Papoian, Vardan; Minehan, Thomas Journal of Organic Chemistry, 2008 , vol. 73, # 18 p. 7376 - 7379

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Citation Number: 45

Abstract

Treatment of aryl iodides with indium metal in the presence of lithium chloride leads to the formation of an organoindium reagent capable of participating in cross-coupling reactions under transition-metal catalysis. Combination with aryl halides in the presence of 5 mol% Cl2Pd (dppf) furnishes biaryl compounds in good yields; similarly, reaction with acyl halides or allylic acetates/carbonates in the presence of 5− 10 mol% palladium catalyst leads to ...

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