Simultaneous Generation of t-BuO and t-BuOO from the Decomposition of 2, 2-Bis (t-butyldioxy) propane. A New Synthetic Method for Introducing a t-BuOO Group into …

Y Watanabe, K Ohta, S Suyama

Index: Watanabe, Yasumasa; Ohta, Kenjiro; Suyama, Shuji Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 8 p. 2063 - 2066

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Abstract

A free-radical synthetic method for introducing a t-BuOO group into various organic substrates has been developed using 2, 2-bis (t-butyldioxy) propane (1a) which can efficiently give two oxygen-centered radicals, t-BuO· and t-BuOO·, by thermolysis. The thermal reaction of 1a with cumene afforded the desired dialkyl peroxide, t-butyl 1-methyl-1- phenylethyl peroxide, in good yield (53% based on 1a reacted) together with an ...

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