Molecules 2012-01-01

Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

Ming Zhang, Ablimit Abdukader, Yong Fu, Chengjian Zhu

Index: Molecules 17(3) , 2812-22, (2012)

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Abstract

An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good to excellent yields at room temperature.

Related Compounds

  • Gold(1+) chloride-...

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