Organic Letters 2007-01-18

Palladium-catalyzed cross-coupling between vinyl halides and tert-butyl carbazate: first general synthesis of the unusual N-Boc-N-alkenylhydrazines.

José Barluenga, Patricia Moriel, Fernando Aznar, Carlos Valdés

Index: Org. Lett. 9 , 275, (2007)

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Abstract

N-Boc-N-alkenylhydrazines, an almost unknown type of compounds, have been prepared with high to moderate yields via palladium-catalyzed cross-coupling between alkenyl halides and tert-butyl carbazate. The present methodology represents the first general way to access this highly functionalized and unusual type of hydrazines. [reaction: see text].


Related Compounds

  • tert-Butyl carbaza...

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