Phosphane??Free Pd0??Catalyzed Cycloamination and Carbonylation with Pd (OAc) 2 and Cu (OAc) 2 in the Presence of K2CO3: Preparation of Benzocyclic Amines …

…, H Senboku, T Masao, T Ohkuma…

Index: Harada, Rika; Nishida, Naoto; Uchiito, Shiho; Onozaki, Yu; Kurono, Nobuhito; Senboku, Hisanori; Masao, Tokuda; Ohkuma, Takeshi; Orito, Kazuhiko European Journal of Organic Chemistry, 2012 , # 2 p. 366 - 379

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Citation Number: 8

Abstract

Abstract Phosphane-free Pd 0-catalyzed intramolecular aromatic amination was studied. o- Halophenethylamines and 3-(o-halophenyl) propylamines were found to be transformed into indolines and quinolines in a catalytic system based on Pd (OAc) 2 and Cu (OAc) 2 in the presence of K 2 CO 3. Application of the method to substrates containing isoquinoline rings– the 1-(o-bromobenzyl)-3, 4-dihydroisoquinolines 6, the 1-(o-bromobenzyl)-1, 2, 3, 4- ...

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