Crystalline six-coordinate phosphorus compounds derived from spiropentaoxyphosphoranes

F Ramirez, VAV Prasad, JF Marecek

Index: Ramirez,F. et al. Journal of the American Chemical Society, 1974 , vol. 96, p. 7269 - 7275

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Citation Number: 22

Abstract

Abstract: Two new types of crystalline substances having six-coordinate phosphorus have been isolated. One of the substances has the charge distribution of a zwitterion and is derived from the reaction of a spiropentaoxyphosphorane with pyridine. The second substance has the charge distribution of an ion pair and is derived from the reaction of the spiropentaoxyphosphorane with phenol and triethylamine. This P (6) adduct differs from ...