4,4'-Dimethoxydiphenylamine

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Names

[ CAS No. ]:
101-70-2

[ Name ]:
4,4'-Dimethoxydiphenylamine

[Synonym ]:
4-Methoxy-N-(4-methoxyphenyl)aniline
Bis-(4-methoxy-phenyl)-amine
Di-p-anisylamine
EINECS 202-968-1
Benzenamine, 4-methoxy-N-(4-methoxyphenyl)-
4,4'-Dimethoxydiphenylamine
MFCD00014895

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
371.1±27.0 °C at 760 mmHg

[ Melting Point ]:
101-102°C

[ Molecular Formula ]:
C14H15NO2

[ Molecular Weight ]:
229.274

[ Flash Point ]:
150.5±13.2 °C

[ Exact Mass ]:
229.110275

[ PSA ]:
30.49000

[ LogP ]:
2.87

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.593

[ Stability ]:
Stability Combustible. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DU9085000
CHEMICAL NAME :
4-Biphenylamine, 4,4'-dimethoxy-
CAS REGISTRY NUMBER :
101-70-2
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C14-H15-N-O2
MOLECULAR WEIGHT :
229.30

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2470 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Behavioral - changes in motor activity (specific assay) Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2500 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Behavioral - changes in motor activity (specific assay) Lungs, Thorax, or Respiration - other changes

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
30 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,175,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 80320 No. of Facilities: 96 (estimated) No. of Industries: 3 No. of Occupations: 15 No. of Employees: 1166 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335-H351

[ Precautionary Statements ]:
P261-P281-P305 + P351 + P338

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R68

[ Safety Phrases ]:
S22-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
DU9085000

[ HS Code ]:
2922299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Thermally stable triaryl amino chromophores with high molecular hyperpolarizabilities Spraul, Bryan K., et al.

Tetrahedron Lett. 45(16) , 3253-3256, (2004)

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