Bis(4-methylphenyl)phosphinous chloride

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Names

[ CAS No. ]:
1019-71-2

[ Name ]:
Bis(4-methylphenyl)phosphinous chloride

[Synonym ]:
Chlorodi(p-tolyl)phosphine
Bis(4-methylphenyl)phosphinous chloride
MFCD01630844
chlorodip-tolylphosphine
Phosphinous chloride, P,P-bis(4-methylphenyl)-
chloro-bis(4-methylphenyl)phosphane

Chemical & Physical Properties

[ Density]:
1.159

[ Boiling Point ]:
346.9±31.0 °C at 760 mmHg

[ Molecular Formula ]:
C14H14ClP

[ Molecular Weight ]:
248.68800

[ Flash Point ]:
163.6±24.8 °C

[ Exact Mass ]:
248.05200

[ PSA ]:
13.59000

[ LogP ]:
6.25

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
n20/D1.501

[ Water Solubility ]:
Reacts with water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S26;S45;S36/S37/S39

[ RIDADR ]:
UN 1760 8/PG 2

[ WGK Germany ]:
3.0

[ Packaging Group ]:
II

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Bis(4-methylphenyl)phosphine oxide
  • Dichloro(dimethylamino)phosphine
  • 4-Tolylmagnesium chloride
  • 4-Bromotoluene
  • Toluene

DownStream

  • 1-[bis(4-methylphenyl)phosphoryl-(4-methylphenyl)phosphoryl]-4-methyl-benzene
  • (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
  • Bis(4-methylphenyl)phosphine oxide
  • Bis(4-methylphenyl)phosphine

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • BIS(4-METHYLPHENYL)PHOSPHINOUS CHLORIDE
  • bis(4-methylphenyl)-diphenylphosphanium,chloride
  • bis(4-methylphenyl)iodanium,chloride
  • bis(4-methylphenyl)bismuth chloride
  • bis(4-methylphenyl)iodanium,iodide
  • bis(4-methoxyphenyl)chlorophosphine
  • (3R)-3-hydroxy-3-(5-propylthiophen-2-yl)propanoic acid
  • (3S)-3-hydroxy-3-(5-propylthiophen-2-yl)propanoic acid
  • 3-Amino-2-methyl-2-(5-propylthiophen-2-yl)propan-1-ol
  • 2-[1-(5-Propylthiophen-2-yl)cyclobutyl]ethan-1-amine
  • 2-Methyl-2-(5-propylthiophen-2-yl)propan-1-ol
  • 2-[1-(5-Propylthiophen-2-yl)cyclopropyl]acetic acid
  • 2-(5-Propylthiophen-2-yl)cyclopropan-1-amine
  • 1-(2,5-dimethylthiophen-3-yl)-N-methylcyclopropan-1-amine
  • 3-(2,5-Dimethylthiophen-3-yl)propanal
  • 3-(But-3-yn-1-yl)-2,5-dimethylthiophene
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