{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde

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Names

[ Name ]:
{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde

[Synonym ]:
MFCD01321229
Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-
2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde
{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde
(tert-Butyldimethylsiloxy)acetaldehyde

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
161.0±23.0 °C at 760 mmHg

[ Melting Point ]:
165-167ºC

[ Molecular Formula ]:
C₈H₁₈O₂Si

[ Molecular Weight ]:
174.313

[ Flash Point ]:
42.7±18.2 °C

[ Exact Mass ]:
174.107605

[ PSA ]:
26.30000

[ LogP ]:
2.61

[ Vapour Pressure ]:
2.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.412

[ Storage condition ]:
below 5° C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1989

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-[(tert-Butyldimethylsilyl)oxy]ethanol
allyl(tert-butyldimethy1)silylether
(Z)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodec-6-ene
tert-butyl-[4-[tert-butyl(dimethyl)silyl]oxybut-2-enoxy]-dimethylsilane
tert-Butyldimethylsilyl chloride
(E)-4-[tert-butyl(dimethyl)silyl]oxybut-2-en-1-ol
3-[tert-butyl(dimethyl)silyl]oxypropane-1,2-diol
2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-ol
Ethyl [(tert-Butyldimethylsilyl)oxy]acetate

DownStream

3-{[tert-Butyl(dimethyl)silyl]oxy}propan-1-ol
Lithium diisopropylamide
(3R,3aS,6aR)-hexahydrofuro[2,3-b]furan-3-ol
(3S,3aS,6aR)-Hexahydrofuro[2,3-b]furan-3-ol
5-[tert-butyl(dimethyl)silyl]oxypent-3-en-2-one
tert-butyl-(3-iodoprop-2-enoxy)-dimethylsilane
(S,E)-N-(2-(TERT-BUTYLDIMETHYLSILYLOXY)ETHYLIDENE)-2-METHYLPROPANE-2-SULFINAMIDE

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Enantioselective total synthesis of (-)-dactylolide.

Org. Lett. 8(6) , 1117-1120, (2006)

[reaction: see text] The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Di...

One-pot enantioselective syntheses of iminosugar derivatives using organocatalytic anti-michael-anti-aza-Henry reactions.

Org. Lett. 12(22) , 5250-3, (2010)

Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaldehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provi...

Organocatalytic asymmetric assembly reactions for the syntheses of carbohydrate derivatives by intermolecular Michael-Henry reactions.

Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20672-7, (2010)

Given the significance of carbohydrates in life, medicine, and industry, the development of simple and efficient de novo methods to synthesize carbohydrates are highly desirable. Organocatalytic asymm...

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