{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde

Modify Date: 2024-01-04 17:24:34

{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde structure	Common Name	{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde
	CAS Number	102191-92-4	Molecular Weight	174.313
	Density	0.9±0.1 g/cm3	Boiling Point	161.0±23.0 °C at 760 mmHg
	Molecular Formula	C₈H₁₈O₂Si	Melting Point	165-167ºC
	MSDS	Chinese USA	Flash Point	42.7±18.2 °C
	Symbol	GHS02, GHS07	Signal Word	Warning

Name	(tert-butyldimethylsilyloxy)acetaldehyde
Synonym	More Synonyms

Density	0.9±0.1 g/cm3
Boiling Point	161.0±23.0 °C at 760 mmHg
Melting Point	165-167ºC
Molecular Formula	C₈H₁₈O₂Si
Molecular Weight	174.313
Flash Point	42.7±18.2 °C
Exact Mass	174.107605
PSA	26.30000
LogP	2.61
Vapour Pressure	2.3±0.3 mmHg at 25°C
Index of Refraction	1.412
Storage condition	below 5° C

MSDS(Chinese)

Symbol	GHS02, GHS07
Signal Word	Warning
Hazard Statements	H226-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xi: Irritant;
Risk Phrases	R36/37/38
Safety Phrases	S26-S36
RIDADR	UN 1989
WGK Germany	3
HS Code	2931900090

Precursor 9
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DownStream 7
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HS Code	2931900090
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Enantioselective total synthesis of (-)-dactylolide.

Org. Lett. 8(6) , 1117-1120, (2006)

[reaction: see text] The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Di...

One-pot enantioselective syntheses of iminosugar derivatives using organocatalytic anti-michael-anti-aza-Henry reactions.

Org. Lett. 12(22) , 5250-3, (2010)

Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaldehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provi...

Organocatalytic asymmetric assembly reactions for the syntheses of carbohydrate derivatives by intermolecular Michael-Henry reactions.

Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20672-7, (2010)

Given the significance of carbohydrates in life, medicine, and industry, the development of simple and efficient de novo methods to synthesize carbohydrates are highly desirable. Organocatalytic asymm...

MFCD01321229

Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde

{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde

(tert-Butyldimethylsiloxy)acetaldehyde