4,5-DIFLUORO-2-METHYLBROMOBENZENE

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Names

[ Name ]:
4,5-DIFLUORO-2-METHYLBROMOBENZENE

[Synonym ]:
(3Ar)-(+)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
(7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-Dioxide
3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aR)-
(+)-10-Camphorsulfonimine
(+)-(camphorsulfonyl)imine
MFCD00013315
(1R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0]dec-4-ene 3,3-dioxide
(3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
337.2±25.0 °C at 760 mmHg

[ Melting Point ]:
229-230ºC(lit.)

[ Molecular Formula ]:
C₁₀H₁₅NO₂S

[ Molecular Weight ]:
213.297

[ Flash Point ]:
157.8±23.2 °C

[ Exact Mass ]:
213.082352

[ PSA ]:
54.88000

[ LogP ]:
0.02

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.693

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(1r)-10-camphorsulfonamide
L(-)-Camphorsulfonic acid
10-camphorsulfonyl chloride

DownStream

(S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM
()-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
(2S)-Bornane-10,2-sultam

Articles

J. Org. Chem. 51 , 2402, (1986)

4,5-Difluoro-2-methylbromobenzene
4,5-Difluoro-2-methylbenzoic acid
4,5-difluoro-2-nitrobenzaldehyde
4,5-Difluoro-2-(propan-2-yloxy)benzoic acid
4,5-Difluoro-2-methylbenzonitrile
(4,5-Difluoro-2-isopropoxyphenyl)methanol
3-(1-(4,5-dimethyl-6-oxo-1,6-dihydropyrimidin-2-yl)-3,5-dimethyl-1H-pyrazol-4-yl)-N-(1-methoxypropan-2-yl)propanamide
3-(1-(4,5-dimethyl-6-oxo-1,6-dihydropyrimidin-2-yl)-3,5-dimethyl-1H-pyrazol-4-yl)-N-(1-phenylethyl)propanamide
3-(1-(4,5-dimethyl-6-oxo-1,6-dihydropyrimidin-2-yl)-3,5-dimethyl-1H-pyrazol-4-yl)-N-(4-phenylbutan-2-yl)propanamide
2-(2-(benzylthio)-6-oxo-1,6-dihydropyrimidin-4-yl)-N-(1-phenylethyl)acetamide
2-(2-((4-fluorobenzyl)thio)-6-oxo-1,6-dihydropyrimidin-4-yl)-N-(4-phenylbutan-2-yl)acetamide
2-(2-((3-methoxybenzyl)thio)-6-oxo-1,6-dihydropyrimidin-4-yl)-N-(1-phenylethyl)acetamide
2-(2-((3-chlorobenzyl)thio)-6-oxo-1,6-dihydropyrimidin-4-yl)-N-(1-phenylethyl)acetamide
2-(2-((2-fluorobenzyl)thio)-6-oxo-1,6-dihydropyrimidin-4-yl)-N-(1-phenylethyl)acetamide
2-(2-(benzylthio)-4-methyl-6-oxo-1,6-dihydropyrimidin-5-yl)-N-(4-phenylbutan-2-yl)acetamide
6-methyl-5-(2-oxo-2-(4-phenylpiperazin-1-yl)ethyl)-2-((1-phenylethyl)thio)pyrimidin-4(3H)-one

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