4,5-DIFLUORO-2-METHYLBROMOBENZENE

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Names

[ Name ]:
4,5-DIFLUORO-2-METHYLBROMOBENZENE

[Synonym ]:
(3Ar)-(+)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
(7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-Dioxide
3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aR)-
(+)-10-Camphorsulfonimine
(+)-(camphorsulfonyl)imine
MFCD00013315
(1R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0]dec-4-ene 3,3-dioxide
(3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
337.2±25.0 °C at 760 mmHg

[ Melting Point ]:
229-230ºC(lit.)

[ Molecular Formula ]:
C₁₀H₁₅NO₂S

[ Molecular Weight ]:
213.297

[ Flash Point ]:
157.8±23.2 °C

[ Exact Mass ]:
213.082352

[ PSA ]:
54.88000

[ LogP ]:
0.02

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.693

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(1r)-10-camphorsulfonamide
L(-)-Camphorsulfonic acid
10-camphorsulfonyl chloride

DownStream

(S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM
()-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
(2S)-Bornane-10,2-sultam

Articles

J. Org. Chem. 51 , 2402, (1986)

4,5-Difluoro-2-methylbromobenzene
4,5-Difluoro-2-methylbenzoic acid
4,5-difluoro-2-nitrobenzaldehyde
4,5-Difluoro-2-(propan-2-yloxy)benzoic acid
4,5-Difluoro-2-methylbenzonitrile
(4,5-Difluoro-2-isopropoxyphenyl)methanol
1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)oxolane-3-carbonyl]-4-methylpiperidine-4-carboxylic acid
2-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclobutyl]-N-(2-methylpropyl)acetamido}acetic acid
4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-{[2-(1-methyl-1H-imidazol-4-yl)ethyl]carbamoyl}butanoic acid
(2R)-2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-phenylpropanamido]-3-hydroxypropanoic acid
1-[2-ethyl-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]cyclopentane-1-carboxylic acid
(2S)-2-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]-3-methylbutanoic acid
5-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-(methylsulfanyl)butanamido]pyridine-3-carboxylic acid
2-[({4-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]phenyl}formamido)methyl]butanoic acid
(2R)-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-phenylpropanamido]butanoic acid
2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-(2-hydroxyethyl)-2,2-dimethylpropanamido]acetic acid

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