4,5-DIFLUORO-2-METHYLBROMOBENZENE

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Names

[ CAS No. ]:
107869-45-4

[ Name ]:
4,5-DIFLUORO-2-METHYLBROMOBENZENE

[Synonym ]:
(3Ar)-(+)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
(7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-Dioxide
3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aR)-
(+)-10-Camphorsulfonimine
(+)-(camphorsulfonyl)imine
MFCD00013315
(1R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0]dec-4-ene 3,3-dioxide
(3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
337.2±25.0 °C at 760 mmHg

[ Melting Point ]:
229-230ºC(lit.)

[ Molecular Formula ]:
C10H15NO2S

[ Molecular Weight ]:
213.297

[ Flash Point ]:
157.8±23.2 °C

[ Exact Mass ]:
213.082352

[ PSA ]:
54.88000

[ LogP ]:
0.02

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.693

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (1r)-10-camphorsulfonamide
  • L(-)-Camphorsulfonic acid
  • 10-camphorsulfonyl chloride

DownStream

  • (S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM
  • ()-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
  • (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
  • (2S)-Bornane-10,2-sultam

Articles

J. Org. Chem. 51 , 2402, (1986)


More Articles

Related Compounds

  • 4,5-Difluoro-2-methylbromobenzene
  • 4,5-Difluoro-2-methylbenzoic acid
  • 4,5-difluoro-2-nitrobenzaldehyde
  • 4,5-Difluoro-2-(propan-2-yloxy)benzoic acid
  • 4,5-Difluoro-2-methylbenzonitrile
  • (4,5-Difluoro-2-isopropoxyphenyl)methanol
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