2-Methylaminoethanol

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Names

[ CAS No. ]:
109-83-1

[ Name ]:
2-Methylaminoethanol

[Synonym ]:
MFCD00002839
2-Hydroxypropanamine
2-(Methylamino)ethanol
(RS)-1-Amino-2-hydroxypropane
1-Amino-2-hydroxypropane
propan-2-ol, 1-amino-
N-Methylethanolamine
2-Methylaminoethanol
(±)-1-Amino-2-propanol
1-Aminopropan-2-ol
(RS)-1-amino-2-propanol
2-Propanol, 1-amino- (8CI,9CI)
UNII:UE40BY1BZW
2-Hydroxy-1-propylamine
2-Propanol, 1-amino-
EINECS 203-710-0
(±)-Isopropanolamine
1-Amino-2-propanol
2-Propanol, 1-amino-, (±)-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
159.9±13.0 °C at 760 mmHg

[ Melting Point ]:
-3 °C

[ Molecular Formula ]:
C3H9NO

[ Molecular Weight ]:
75.110

[ Flash Point ]:
73.9±0.0 °C

[ Exact Mass ]:
75.068413

[ PSA ]:
32.26000

[ LogP ]:
-0.96

[ Vapour density ]:
2.6 (vs air)

[ Vapour Pressure ]:
0.9±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.440

[ Stability ]:
Stable. Combustible. Incompatible with oxidizing agents.

[ Water Solubility ]:
miscible

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KL6650000
CHEMICAL NAME :
Ethanol, 2-(methylamino)-
CAS REGISTRY NUMBER :
109-83-1
BEILSTEIN REFERENCE NO. :
1071196
LAST UPDATED :
199806
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C3-H9-N-O
MOLECULAR WEIGHT :
75.13
WISWESSER LINE NOTATION :
Q2M1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 1/20/1972 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2340 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1330 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 12,486,1968
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1802 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - coma Lungs, Thorax, or Respiration - other changes
REFERENCE :
AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 225,428,1955
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1070 uL/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536158 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4016 No. of Facilities: 7733 (estimated) No. of Industries: 36 No. of Occupations: 28 No. of Employees: 39013 (estimated) No. of Female Employees: 11887 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312-H314-H335-H373

[ Precautionary Statements ]:
P280-P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Target Organs ]:
Epididymus, Kidney, Liver, Testes, ovary, spleen

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R21/22;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
KL6650000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29221980

Synthetic Route

Precursor & DownStream

Precursor

  • N-Benzyl-N-methylethanolamine
  • Glycine, N-methyl-, ethyl ester
  • Formaldehyde
  • 2-Aminoethanol
  • Methanol
  • ETHYLENE OXIDE
  • methylamine
  • diazomethane
  • 2-Chloroethanol
  • Oxazole

DownStream

  • methylamine
  • Sarcosine sodium salt
  • (2-Methoxyethyl)-methylamine
  • 2-chloro-N-methylethanamine
  • 4-[2-hydroxyethyl(methyl)amino]-1-thiophen-2-ylbutan-1-one
  • 4-[2-hydroxyethyl(methyl)amino]-1-phenylbutan-1-one

Customs

[ HS Code ]: 2922199090

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • 1,1-dimethyl-2-methylaminoethanol
  • 2-methylaminoethanol hydrochloride
  • 1-(3-pyridyl)-2-methylaminoethanol
  • 1-(4-Pyridyl)-2-methylaminoethanol
  • 1-(m-Nitrophenyl)-2-methylaminoethanol
  • 1-(4-Hydroxyphenyl)-2-methylaminoethanol
  • 2-Chloro-N-[2,2,2-trifluoro-1-(1-methylpyrrol-3-yl)ethyl]acetamide
  • 4-(2-chloroacetyl)-1-imino-3,4-dihydro-2H-1lambda6,4-benzothiazin-1-one
  • (1R,6S)-5-(2-Chloroacetyl)-2-methyl-2,5-diazabicyclo[4.1.0]heptan-3-one
  • 2-Chloro-N-[6-(4-fluorophenyl)-2-methylpyrimidin-4-yl]acetamide
  • 3-(2-Chloro-6-fluorophenyl)-4-(2-chloroacetyl)piperazin-2-one
  • Methyl 5-[(2-chloroacetamido)methyl]pyridine-3-carboxylate
  • 2-Chloro-N-[(2-sulfamoylthiophen-3-yl)methyl]acetamide
  • 2-Chloro-N-[(2S,3S)-1-cyclopropyl-2-(2-methylpyrazol-3-yl)-5-oxopyrrolidin-3-yl]acetamide
  • 2-Chloro-1-spiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-ylethanone
  • 1'-(2-Chloroacetyl)-N,N-dimethylspiro[4,7-dihydropyrazolo[5,1-c][1,4]oxazine-6,4'-piperidine]-2-carboxamide